This essay introduces three precious literature materials dated back to the end of Li Dynasty of Korea. Firstly，a discourse on politics written by Mr. Zhou Weihan，a successful candidate in the highest imperial examination，together with comments given by the examiner. It reflects the far-reaching influence of Chinese Imperial Examination Culture toward Korea as Korean imperial examination is similar with China both in its content and form. Secondly，a manuscript called Complete Classic Ancient Prose，Volume 2，by Mr. Li Xueyong，a Korean scholar. It mainly collects poems written by famous Chinese scholars since Tang and Song Dynasty，and is a proof that Chinese Confucianism culture is deeply rooted in the Korean peninsular. Thirdly，the Korea Hunan Chorography written by Korean scholars during the regime of Emperor Tongzhi and Guangxu. Although it was published in 1934 and underwent the censor of Japanese colonial rulers，the inscriptions and characters maintain the evidence of Korean patriots’ rebellion against powerful and treacherous court officials and Japanese colonial rulers. These three cultural relics not only reflect history and culture by the end of Li Dynasty，but also prove the long history of Sino-Korea cultural exchange.